项目负责人：伊廷锋
成果所属类别：【新材料】【新能源产业】【绿色低碳】
团队介绍：
伊廷锋教授团队由1位教授、1位副教授及2位讲师组成，长期致力于电催化材料、能源存储与转换器件的设计与开发。团队主持完成20余项科研项目，其中国家自然科学基金项目8项，省部级项目8项。到2025年4月为止，共发表SCI期刊论文230余篇，H因子为60，他引11000余次，先后有28篇论文为ESI高引论文，8篇论文入选热点(ESI HOT paper)论文，33篇论文被引用超百次。具备扎实的科研基础与成果转化能力。
成果简介：
（一）本技术在锌负极上设计并构建了一种稳定的多功能ZTO（ZnTiO3）绝缘涂层，可有效抑制枝晶形成和锌负极腐蚀。通过结合实验分析和密度泛函理论DFT计算，研究人员发现ZTO与Zn(002)晶面的高度匹配性使其在反复充放电过程中能与锌形成稳定界面。这一共格界面可调控锌离子通量分布，诱导Zn²⁺优先沿(002)晶面取向沉积，同时保持离子传输连续性。此外，ZTO通过Zn/O位点排斥/吸附活性H₂O中的H，减轻了水相关副反应。优化后的Zn-ZTO结构在对称电池中表现出卓越的耐久性，在1 mA cm-2/1 mAh cm-2条件下实现了超过8,800小时的优异循环稳定性。该研究拓展了保护层筛选策略，深化了对Zn²⁺沉积/剥离机制的理解，为开发稳定锌金属电池奠定了基础。
（二）本技术开发了一种PEO基三元盐固态电解质，通过在PEO基体中引入双三氟甲烷磺酰亚胺锂（LiTFSI），双氟磺酰亚胺锂（LiFSI）和LiNO3三种锂盐，从而在锂金属阳极和电解质之间形成了稳定的富含Li3N-LiF的原位固体电解质界面层（SEI层）。该电解质具有良好的机械性能和高的Li+迁移数。值得注意的是，组装的Li/PEO-LiTFSI-LiFSI-LiNO3/LiFePO4全固态电池表现出优异的循环稳定性（在2 C下可循环约2200圈）。
专利以及成果情况：
发表SCI论文11篇，具体成果如下：
[1] Kang-Rui Ren, Lang Chen, Chao-Zhi Liu, Yue Tian, Xin-Yi Leng, Ming-Na Jiang, Zhuo Han, Guan-You Xiao, Guang-Ning Xu, Zhan Yu, Peng-Fei Wang, Ying Xie*, Yan-Bing He*, Ting-Feng Yi*, Ligand field electronic state regulation of monoclinic Prussian white toward highly stable sodium-ion batteries, Advanced Materials, 2025, 37, 2507960. (IF 26.8)
[2] Taotao Li, Nan Zhang, Bingchen Liu, Pengfei Wang, Zonglin Liu, Yuange Wang, Dinghao Xu, Hao Tian, Qianyu Zhang*, Ting-Feng Yi*, Unlocking the critical role of cations doping in MnO2 cathode with enhanced reaction kinetics for aqueous zinc ion batteries, Advanced Functional Materials, 2025, 35(20), 2423755. (IF 19)
[3] Ying Li, Yi-Han Zhao, Jingyu Wang, Dinghao Xu, Yuange Wang, Pengfei Wang, Zonglin Liu, Qinzhi Lai, Jie Shu, Qianyu Zhang*, Ting-Feng Yi*, Epitaxial substrate engineering enables ultrastable zinc anodes via low-lattice-mismatch interface-induced dendrite regulation, Advanced Functional Materials, 2025, 35, 09963. (IF 19)
[4] Bo-Xuan Zhang, Wen-Juan Liu, Yue Tian, Lang Chen, Zhuo-Yun Song, Qi-Min Fang, Shengxue Yan, Jie Shu, Ting-Feng Yi*, Optimization strategies for high performance zinc-ion hybrid supercapacitors: advances in materials, interfaces and devices, Energy Storage Materials, 2025, 80, 104449. (IF 20.2)
[5] Lu-Lu Zhao, Yi-Han Zhao, Yi-Meng Wu, Peng-Fei Wang, Zong-Lin Liu, Qian-Yu Zhang, Jie Shu, Ting-Feng Yi*, Everything in aqueous zinc-ion batteries may be Prussian blue analogues: From cathode materials to electrolyte additives applications, Energy Storage Materials, 2025, 78, 104299. (IF 20.2)
[6] Lu-Lu Zhao, Jun-Wei Yin, Bing-Chen Liu, Peng-Fei Wang, Zong-Lin Liu, Ying Xie*, Jie Shu, Qian-Yu Zhang, Ting-Feng Yi*, Construction of high-performance aqueous zinc-ion batteries by guest pre-intercalation MnO2-based cathodes, Advances in Colloid and Interface Science, 2025, 341, 103499. (IF 19.3)
[7] Lu-Lu Zhao, Jing-Yu Wang, Yi-Meng Wu, Peng-Fei Wang, Zong-Lin Liu, Jie Shu, Ting-Feng Yi*, Qiaobao Zhang*, Unlocking the multidimensional application and optimization mechanism of MOFs materials in aqueous zinc ion batteries, Journal of Energy Chemistry, 2025, 111, 249-273. (IF 14.9)
[8] Zheng-Xiao Li, Yi-Meng Wu, Jun-Wei Yin, Peng-Fei Wang, Zong-Lin Liu, Yan-Xuan Wen, Jun-Hong Zhang*, Yan-Rong Zhu*, Ting-Feng Yi*, Emerging modification strategies for layered Fe-based oxide cathodes toward high-performance sodium-ion batteries, Journal of Energy Chemistry, 2025, 107, 122-147. (IF 14.9)
[9] Hong-Yan Liu, Xin-Yu Liu, Nan Zhang, Peng-Fei Wang*, Zong-Lin Liu, Jie Shu, Ting-Feng Yi*, Functional ternary salt construction enabling an in-situ Li3N/LiF-enriched interface for ultra-stable all-solid-state lithium metal batteries, Journal of Energy Chemistry, 2025, 101, 68-75. (IF 14.9)
[10] Yi-Han Zhao, Shan Zhao, Xin-Yu Liu, Peng-Fei Wang, Zong-Lin Liu, Jie Shu, Ting-Feng Yi*, Decoding the coordination environment engineering of non-noble metal-nitrogen-carbon: from microstructure to oxygen electrocatalytic performance, Journal of Energy Chemistry, 2025, 109, 952–974. (IF 14.9)
[11] Nan Zhang, Xing-Qi Chen, Xiaoting Lin, Peng-Fei Wang*, Zong-Lin Liu, Jie Shu, Ping He*, Ting-Feng Yi*, Targeting stability: Recent progress and perspectives on both anode and cathode interface of halide solid electrolytes, Journal of Energy Chemistry, 2025, 109, 497-517. (IF 14.9)
[12] Jun-Wei Yin, Yi-Meng Wu, Xin-Yu Liu, Jing Li, Peng-Fei Wang, Zong-Lin Liu, Lin-Lin Wang, Jie Shu, Ting-Feng Yi*, Insights into degradation mechanisms and engineering strategies of layered manganese-based oxide cathodes for sodium-ion battery, Green Energy & Environment, 2025, in process (IF 14.6)
[13] Ying Li, Jin-Peng Qu, Jing-Yu Wang, Pengfei Wang, Zonglin Liu, Jie Shu, Ting-Feng Yi*, Unlocking the electrochemical ammonium storage performance of copper intercalated hexacyanoferrate, Chemical Engineering Journal, 2025, 503, 158266. (IF 13.2)
[14] Ying Li, Nan Zhang, Jing-Yu Wang, Pengfei Wang, Zonglin Liu, Yan-Rong Zhu*, Jie Shu, Ting-Feng Yi*, Construction of high-voltage aqueous Zn-MnO2 batteries based on polar small-molecule organic acid-induced MnO2/Mn2+ reactions, Chemical Engineering Journal, 2025, 507, 160415. (IF 13.2)
[15] Lang Chen, Yue Tian, Bing-Chen Liu, Bo-Xuan Zhang, Kang-Rui Ren, Zhuo-Yun Song, Pengfei Wang, Zonglin Liu, Qianyu Zhang, Jie Shu, Ting-Feng Yi*, Stabilizing zinc anode with multifunctional glycine copper additive, Chemical Engineering Journal, 2025, 522, 167617. (IF 13.2)